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TECHNOLOGY: Sulpholane Extraction Technology for Production of Pure Benzene and Toluene

APPLICATIONS:

  • For the production of pure aromatics like benzene, toluene and/or xylene from aromatic rich feed stocks such as catalytic reformats and hydrogenated pyrolysis gasoline
  • Production of special boiling point solvents.
  • Production of low aromatic feedstocks for fertilizer and petrochemical plants.

TECHNOLOGY STATUS:  
  • Jointly developed with EIL
  • Two commercial units at BPCL,Mumbai,and KRL Kochhi in operation.
ProductsBenzeneTolueneON STREAM
1.BPCL,MUMBAI98,000 TPA17,000 TPA1985
2.KRL,KOCHHI90,000 TPA17,000 TPA1987
  • Technology offered to other proposed units in country.
SALIENT FEATURES:
  • Use of Sulpholane, as extraction solvent, possesses a favorable combination of solvent power and selectivity resulting in the production of aromatic hydrocarbons in high purity (99.9% +) and yields( Aliphatic impurities < 300 ppm)
  • Flexible in handling wide boiling range feedstock. Heart cut feed preparation is not required .
  • Low utilities requirement as compared to extractive distillation process.
  • Low solvent loss
  • Plant adaptations for future needs.
Techno-Economics:                 
  • Maximum units operational world over, are based on sulpholane process
  • The typical costs (including fractionators) for a unit to process 230,000 MTPA of feed containing about 70 wt.% aromatics are as follows: Investment Million US $ 21.0 (Basis: turnkey installation, battery limits, Indian location, March 2004) Utilities Electricity, MW 0.5 Steam, MT/Hr 30 Water, cooling, MT/Hr 950 Inert Gas, NM3/Hr 100
  • Payback period < 3 yrs